Exploring the influence of the surface resistance of nanoporous particles on molecular transport
نویسنده
چکیده
Molecular transport through the nanoporous particles, in particular, zeolite crystallites, is influenced both by intracrystalline diffusion and surface resistance. In comparison to zeolite crystallites with ideal structure, molecular transport in real-world zeolite particles may often be influenced by the surface barriers resulting from various defects at the surface of the crystallite. The potentials of the combined use of the pulsed field gradient NMR and dynamic Monte Carlo simulations for exploration of the surface permeability of nanoporous particles are demonstrated.
منابع مشابه
Influence of Interface Thermal Resistance on Relaxation Dynamics of Metal-Dielectric Nanocomposite Materials under Ultrafast Pulse Laser Excitation
Nanocomposite materials, including noble metal nanoparticles embedded in a dielectric host medium, are interesting because of their optical properties linked to surface plasmon resonance phenomena. For studding of nonlinear optical properties and/or energy transfer process, these materials may be excited by ultrashort pulse laser with a temporal width varying from some femtoseconds to some hund...
متن کاملEffect of Nanoporous Anodic Aluminum Oxide (AAO) Characteristics On Solar Absorptivity
Nanoporous anodic aluminum oxide (AAO) has been used in many different fields of science and technology, due to its great structural characteristics. Solar selective surface is an important application of this type porous material. This paper investigates the effect of nanoporous AAO properties, including; film thickness, pore area percentage and pore diameter, on absorption spectra in the rang...
متن کاملInfluence of electroplating parameters on microstructure and amount of ceramic particle deposition in Ni-Co-CeO2-ZrO2 composite coating
Austenitic stainless steels are high performance steels that have various applications in solid oxide fuel cells and boiler tubes under high temperature operating conditions. The Cr2O3 oxide layer formed on the steel surface becomes unstable at high temperatures and reduces the oxidation resistance of the steel. Therefore, protection of these steels at high temperatures is essential. Therefore,...
متن کاملImproving the surface wear resistance of aluminum by electrical discharge process
In this study electrical discharge process was used to increase surface wear resistance of pure aluminum. Pulse-on-time and pulse current were considered as input parameters of the electrical discharge process. Experimental results reveal that the electrical discharge process is a successful method for improving the surface wear resistance of aluminum, so that this method has greatly increased ...
متن کاملExploring mechanism of xanthate adsorption on chalcopyrite surface: An atomic force microscopy study
In this work, adsorption of the potassium amyl xanthate collector on the pure chalcopyrite surface was studied by applying atomic force microscopy (AFM). The adsorption experiments were carried out at different concentrations of the collector and at diverse pH values in the presence or absence of exterior ions. The changes occurring in the surface morphology of chalcopyrite due to the collector...
متن کامل